Photomask Manufacturing Deep-Dive: Shin-Etsu, AGC, and Hoya – From Quartz to Soda Lime Substrates with Spin-Coated Photoresist

Introduction – Addressing Core Industry Pain Points
The global semiconductor, flat-panel display (FPD), and precision optics industries face a persistent challenge: producing photomasks with high-resolution pattern fidelity, low defect density, and dimensional stability for advanced lithography processes (EUV, DUV, i-line, g-line). Photomasks are master templates used to project circuit patterns onto wafers (semiconductors) or glass substrates (FPDs). The starting material—mask blanks—must have ultra-flat surfaces, uniform light-blocking films, and defect-free photoresist coatings. Foundries, IDMs, and display manufacturers increasingly demand chrome mask blanks with spin-coated photoresist—photomask blanks consisting of a transparent substrate (typically synthetic quartz for high transmission, low thermal expansion, or high-grade soda lime glass for cost-sensitive applications) coated with a uniform, dense chrome (Cr) light-blocking film (40-100nm thickness, 2-5% reflectivity), followed by a uniform photoresist layer (e-beam sensitive or laser sensitive) on top. The chrome film blocks exposure light (UV, DUV, EUV), while the photoresist enables precise pattern transfer during electron-beam or laser writing. This type of blank is a critical intermediate material for fabricating photomasks in semiconductor (logic, memory, foundry), flat-panel display (LCD, OLED, microLED), and precision optical device manufacturing (diffractive optics, gratings), offering high coating uniformity (thickness variation <1-2%), strong adhesion (chrome to glass, resist to chrome), and excellent dimensional stability (low thermal expansion). Global Leading Market Research Publisher QYResearch announces the release of its latest report “Chrome Mask Blanks – Global Market Share and Ranking, Overall Sales and Demand Forecast 2026-2032″. Based on current situation and impact historical analysis (2021-2025) and forecast calculations (2026-2032), this report provides a comprehensive analysis of the global Chrome Mask Blanks market, including market size, share, demand, industry development status, and forecasts for the next few years.

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https://www.qyresearch.com/reports/6095775/chrome-mask-blanks

Market Sizing & Growth Trajectory
The global market for Chrome Mask Blanks was estimated to be worth US$ 3,228 million in 2025 and is projected to reach US$ 4,921 million, growing at a CAGR of 6.3% from 2026 to 2032. In 2024, global Chrome Mask Blanks production reached approximately 234,700 square meters, with an average global market price of around US$ 13,750 per square meter (based on US$3,228M/0.235M m² ≈ $13,750). According to QYResearch’s interim tracking (January–June 2026), the market is driven by: (1) advanced semiconductor nodes (3nm, 2nm, 1.4nm) requiring high-end quartz mask blanks, (2) flat-panel display (FPD) capacity expansion (Gen 10.5+ for 65-85″ TVs), (3) EUV lithography adoption (13.5nm wavelength) requiring defect-free, ultra-low thermal expansion mask blanks. The quartz substrate segment dominates (65-70% market share, high transmission (DUV/EUV), low thermal expansion (CTE 0.5 ppm/°C)), with soda lime (SL) substrate (20-25%, cost-sensitive, i-line/g-line) and others (5-10%). Semiconductors account for 60-65% of demand, flat-panel displays 25-30%, hard disk drives (HDD) 5-8%, and others (optics, MEMS) 2-5%.

独家观察 – Chrome Mask Blank Structure and Specifications

Parameter Quartz Substrate Soda Lime (SL) Substrate
Market share (2025) 65-70% 20-25%
Application Advanced nodes (DUV (193nm), EUV (13.5nm), high-end photomasks) Mature nodes (i-line (365nm), g-line (436nm)), cost-sensitive masks
Transmission (193nm DUV) >90% <50% (absorbs)
Thermal expansion coefficient (CTE) 0.5 ppm/°C (low) 9 ppm/°C (high)
Flatness (μm over 6″ x 6″) <0.5-1μm <1-2μm
Surface roughness (RMS) <0.1-0.2nm <0.5nm
Chrome film thickness 40-100nm (Cr, CrO, CrON) 40-100nm
Chrome reflectivity 2-5% (low) 2-5%
Photoresist type e-beam (PMMA, ZEP, HSQ), laser e-beam, laser (i-line, g-line)
Photoresist thickness 100-500nm 100-500nm
Substrate size (mm) 152×152 (6″), 229×229 (9″), 152×152, 228×228, 254×254 152×152 (6″), 228×228 (9″)
Cost per square meter $15,000-25,000 $3,000-6,000

From a mask blank manufacturing perspective (substrate polishing, thin-film deposition, photoresist coating), chrome mask blanks differ from uncoated glass substrates through: (1) super-polished surface (Ra <0.2nm for quartz), (2) chrome sputter deposition (DC magnetron, Cr or CrO targets, thickness uniformity <1%), (3) photoresist spin coating (uniformity <2%, defect density <0.01-0.1/cm²), (4) hardmask layers (CrO, CrON for etch resistance), (5) anti-reflective coating (ARC) for reduced reflectivity.

Six-Month Trends (H1 2026)
Three trends reshape the market: (1) EUV mask blank development – Reflective mask blanks (Mo/Si multilayers + capping layer + absorber) for EUV (13.5nm), requiring defect-free substrates (<0.001 defects/cm²), ultra-low thermal expansion (ULE, Zerodur), and specialized deposition (ion beam deposition); (2) Large-area mask blanks for FPDs – Gen 10.5+ substrates (2940mm x 3370mm) for 65-85″ TV panels, requiring square meter-scale chrome mask blanks (multiple-up patterning); (3) Photoresist innovation – High-sensitivity e-beam resists (ZEP, HSQ) for faster writing time (2-5x throughput), reducing mask manufacturing cost.

User Case Example – EUV Mask Blank Development, Japan
A Japanese mask blank supplier (Shin-Etsu) developed EUV mask blanks (reflective, Mo/Si multilayer, Ru capping layer, TaBN absorber) for 3nm logic node (TSMC, Samsung). Specifications: substrate flatness <50nm (over 6″ x 6″), defect density <0.001/cm² (zero printable defects), multilayer reflectivity >68% at 13.5nm. Results (2025): mask blank cost $10,000-15,000 per unit (vs. $3,000-5,000 for DUV mask blanks). Supplier shipped 1,000+ units for 3nm pilot line.

Technical Challenge – Defect Density and Substrate Flatness
A key technical challenge for chrome mask blank manufacturers is achieving extremely low defect density (<0.01-0.001/cm² for advanced nodes) and sub-micron flatness for high-NA lithography (EUV, DUV immersion):

Parameter Requirement (Advanced Node) Manufacturing Challenge Mitigation Strategy
Defect density (substrate) <0.001/cm² (EUV), <0.01-0.1/cm² (DUV) Particles (dust, debris), pits, scratches, inclusions in quartz Class 1/ISO 3 cleanroom (min 0.1μm particles), automated inspection (laser scattering, AFM), multi-step cleaning (wet, megasonic), protective film
Defect density (chrome film) <0.01/cm² Pinholes, nodules, particles during sputtering High-purity targets (Cr 99.99%), DC magnetron sputtering (low particle generation), in-situ inspection (darkfield), repair (focused ion beam (FIB))
Defect density (photoresist) <0.01/cm² Particles, bubbles, striations (non-uniform coating) Point-of-use filtration (0.02-0.1μm), spin coating (dynamic dispense, edge bead removal), Class 1 environment
Substrate flatness (6″ x 6″) <0.5μm (peak-to-valley) Warpage from polishing, mounting, film stress Double-side polishing (DSP), stress-balanced chrome films (Cr + CrO), stress relief anneal
Surface roughness (RMS) <0.1nm (EUV), <0.2-0.5nm (DUV) Polishing defects, subsurface damage Chemical mechanical polishing (CMP), magnetorheological finishing (MRF), ion beam figuring (IBF)

Inspection: Automated mask blank inspection (laser scattering (KLA-Tencor), UV inspection) for defects >30-100nm. Repair: focused ion beam (FIB) for chrome defects, atomic force microscopy (AFM) for flatness.

独家观察 – Quartz vs. Soda Lime Substrates

Parameter Quartz Substrate Soda Lime (SL) Substrate
Market share (2025) 65-70% 20-25%
Projected CAGR (2026-2032) 6-8% 3-5%
Transmission (193nm DUV) >90% <50% (not suitable)
Transmission (365nm i-line) >90% >85% (suitable)
Thermal expansion coefficient (CTE) 0.5 ppm/°C (low) 9 ppm/°C
Flatness (6″ x 6″) <0.5-1μm <1-2μm
Surface roughness (RMS) <0.1-0.2nm <0.5nm
Maximum substrate size 254x254mm (10″) 228x228mm (9″)
Application nodes 193nm DUV (ArF), 248nm DUV (KrF), EUV (13.5nm) i-line (365nm), g-line (436nm)
Primary customers Logic (5nm, 3nm, 2nm), DRAM (1a, 1b, 1c), NAND (2xxL, 3xxL) Mature nodes (90nm, 130nm, 180nm+), MEMS, power devices, analog
Price per square meter $15,000-25,000 $3,000-6,000
Key suppliers (quartz) Shin-Etsu (Japan, market leader), Hoya (Japan), Tosoh (Japan), ULCOAT (Japan), SKC (Korea), CTS (China), BKL (Korea), Telic (Korea) AGC (Japan), S&S Tech (Korea), CTS (China), Anhui Hechen (China), Hunan Omnisun (China), Changsha Shaoguang (China), Chengdu Zhongkezhuoer (China)

Downstream Demand & Competitive Landscape
Applications span: Semiconductors (photomask for logic (CPU, GPU, FPGA), memory (DRAM, NAND flash), foundry – largest segment, 60-65%, highest value, driven by advanced nodes), Flat-panel Displays (LCD, OLED, microLED photomasks for TV, monitor, smartphone, tablet displays – 25-30%, large-area masks), Hard Disk Drives (HDD photomasks for read/write head manufacturing – 5-8%, declining due to SSD adoption), Others (MEMS, power devices, analog, optics, gratings – 2-5%). Key players: Shin-Etsu (Japan, quartz mask blanks leader), AGC (Japan, soda lime and quartz), Hoya (Japan, quartz, EUV mask blanks), S&S Tech (Korea, FPD mask blanks), Tosoh (Japan, quartz), ULCOAT (Japan), SKC (Korea), CTS (China), BKL (Korea), Telic (Korea), Hunan Omnisun Information Material (China), Changsha Shaoguang Core Material (China), Chengdu Zhongkezhuoer (China), Anhui Hechen New Material (China). The market is dominated by Japanese suppliers (Shin-Etsu, Hoya, AGC, Tosoh, ULCOAT) for high-end semiconductor mask blanks, with Korean (S&S Tech, SKC, BKL, Telic) and Chinese (CTS, Hunan Omnisun, Changsha Shaoguang, Chengdu Zhongkezhuoer, Anhui Hechen) suppliers gaining share in FPD and mature-node semiconductor segments.

Segmentation Summary
The Chrome Mask Blanks market is segmented as below:

Segment by Substrate – Quartz Substrate (dominant, 65-70%, advanced nodes, high cost), Soda Lime (SL) Substrate (20-25%, mature nodes, cost-sensitive), Others (5-10%, ULE, Zerodur, glass-ceramic)

Segment by Application – Semiconductors (largest, 60-65%), Flat-panel Displays (25-30%), Hard Disk Drives (5-8%), Others (2-5%)

Contact Us:
If you have any queries regarding this report or if you would like further information, please contact us:
QY Research Inc.
Add: 17890 Castleton Street Suite 369 City of Industry CA 91748 United States
EN: https://www.qyresearch.com
E-mail: global@qyresearch.com
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